GREP C11935

Selected compound(s)

C11935 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA

Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions | Reported reactions]

Suggested reactions

[Fig] 1.1.1.- : 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + NAD+ = 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + NADH + H+
[Fig] 1.1.1.- : 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + NADPH + H+ = 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + NADP+
[Fig] 1.1.3.- : 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + O2 = 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + H2O2
[Fig] 1.1.4.- : 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + 1,4-Dithiothreitol = 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + Oxidized dithiothreitol
[Fig] 1.1.5.- : 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + Coenzyme F420 = 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + Reduced coenzyme F420
[Fig] 1.1.5.- : 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + Reduced thioredoxin = 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + Oxidized thioredoxin
[Fig] 1.1.5.- : 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + CoQH2 = 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + CoQ
[Fig] 1.1.99.- : 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + FAD = 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + FADH2
[Fig] 1.14.11.- : Perillyl-CoA + O2 + 2-Ketoglutaric acid = 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + CO2 + Butanedionic acid
[Fig] 1.14.13.- : 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + H2O + NAD+ = Perillyl-CoA + NADH + O2 + H+
[Fig] 1.14.13.- : 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + H2O + NADP+ = Perillyl-CoA + NADPH + O2 + H+
[Fig] 1.14.16.- : 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + 6,7-Dihydrobiopterin + H2O = Perillyl-CoA + 2-Amino-6-(1,2-dihydroxypropyl)-5,6,7,8-tetrahydoro-4(1H)- pteridinone + O2
[Fig] 1.14.17.- : Perillyl-CoA + Vitamin C + O2 = 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + Dehydroascorbate + H2O

Reported reactions

[Fig] EC 1.1.-.- : 2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + Acceptor = 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + Reduced acceptor
[Fig] EC 3.7.1.- : 4-Isopropenyl-2-ketocyclohexane-1-carboxyl-CoA + H2O = 3-Isopropenylpimelyl-CoA

GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.