GREP C11930

Selected compound(s)

C11930 dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran

Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions | Reported reactions]

Suggested reactions

[Fig] 1.1.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADPH + H+ = dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose + NADP+
[Fig] 1.1.1.- : dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose + NAD+ = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADH + H+
[Fig] 1.1.3.- : dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose + O2 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O2
[Fig] 1.1.4.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + 1,4-Dithiothreitol = dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose + Oxidized dithiothreitol
[Fig] 1.1.5.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Reduced thioredoxin = dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose + Oxidized thioredoxin
[Fig] 1.1.5.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + CoQH2 = dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose + CoQ
[Fig] 1.1.5.- : dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose + Coenzyme F420 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Reduced coenzyme F420
[Fig] 1.1.99.- : dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose + FAD = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + FADH2
[Fig] 1.3.1.- : dTDP-4-oxo-2,6-dideoxy-alpha-D-glucose + NAD+ = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADH + H+
[Fig] 1.3.1.- : dTDP-4-oxo-2,6-dideoxy-L-glucose + NAD+ = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADH + H+
[Fig] 1.3.1.- : dTDP-4-oxo-2,6-dideoxy-D-glucose + NAD+ = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADH + H+
[Fig] 1.3.1.- : dTDP-4-oxo-2,6-dideoxy-L-mannose + NAD+ = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADH + H+
[Fig] 1.3.1.- : dTDP-4-oxo-2,6-dideoxy-D-allose + NAD+ = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADH + H+
[Fig] 1.3.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADPH + H+ = dTDP-4-oxo-2,6-dideoxy-alpha-D-glucose + NADP+
[Fig] 1.3.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADPH + H+ = dTDP-4-oxo-2,6-dideoxy-L-glucose + NADP+
[Fig] 1.3.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADPH + H+ = dTDP-4-oxo-2,6-dideoxy-D-glucose + NADP+
[Fig] 1.3.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADPH + H+ = dTDP-4-oxo-2,6-dideoxy-L-mannose + NADP+
[Fig] 1.3.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADPH + H+ = dTDP-4-oxo-2,6-dideoxy-D-allose + NADP+
[Fig] 1.3.3.- : dTDP-4-oxo-2,6-dideoxy-alpha-D-glucose + O2 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O2
[Fig] 1.3.3.- : dTDP-4-oxo-2,6-dideoxy-L-glucose + O2 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O2
[Fig] 1.3.3.- : dTDP-4-oxo-2,6-dideoxy-D-glucose + O2 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O2
[Fig] 1.3.3.- : dTDP-4-oxo-2,6-dideoxy-L-mannose + O2 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O2
[Fig] 1.3.3.- : dTDP-4-oxo-2,6-dideoxy-D-allose + O2 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O2
[Fig] 1.3.4.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + 1,4-Dithiothreitol = dTDP-4-oxo-2,6-dideoxy-alpha-D-glucose + Oxidized dithiothreitol
[Fig] 1.3.4.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + 1,4-Dithiothreitol = dTDP-4-oxo-2,6-dideoxy-L-glucose + Oxidized dithiothreitol
[Fig] 1.3.4.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + 1,4-Dithiothreitol = dTDP-4-oxo-2,6-dideoxy-D-glucose + Oxidized dithiothreitol
[Fig] 1.3.4.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + 1,4-Dithiothreitol = dTDP-4-oxo-2,6-dideoxy-L-mannose + Oxidized dithiothreitol
[Fig] 1.3.4.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + 1,4-Dithiothreitol = dTDP-4-oxo-2,6-dideoxy-D-allose + Oxidized dithiothreitol
[Fig] 1.3.5.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + CoQH2 = dTDP-4-oxo-2,6-dideoxy-alpha-D-glucose + CoQ
[Fig] 1.3.5.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + CoQH2 = dTDP-4-oxo-2,6-dideoxy-L-glucose + CoQ
[Fig] 1.3.5.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + CoQH2 = dTDP-4-oxo-2,6-dideoxy-D-glucose + CoQ
[Fig] 1.3.5.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + CoQH2 = dTDP-4-oxo-2,6-dideoxy-L-mannose + CoQ
[Fig] 1.3.5.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + CoQH2 = dTDP-4-oxo-2,6-dideoxy-D-allose + CoQ
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-alpha-D-glucose + FAD = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + FADH2
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-alpha-D-glucose + Coenzyme F420 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Reduced coenzyme F420
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-L-glucose + FAD = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + FADH2
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-L-glucose + Coenzyme F420 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Reduced coenzyme F420
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-D-glucose + FAD = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + FADH2
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-D-glucose + Coenzyme F420 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Reduced coenzyme F420
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-L-mannose + FAD = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + FADH2
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-L-mannose + Coenzyme F420 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Reduced coenzyme F420
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-D-allose + FAD = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + FADH2
[Fig] 1.3.99.- : dTDP-4-oxo-2,6-dideoxy-D-allose + Coenzyme F420 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Reduced coenzyme F420
[Fig] 1.4.1.- : dTDP-3-amino-2,3,6-trideoxy-D-threo-hexopyranos-4-ulose + H2O + NAD+ = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADH + Ammonia
[Fig] 1.4.1.- : dTDP-3-amino-2,3,6-trideoxy-D-threo-hexopyranos-4-ulose + H2O + NAD+ = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + NADH + H+ + Ammonia
[Fig] 1.4.1.- : dTDP-3-amino-2,3,6-trideoxy-D-threo-hexopyranos-4-ulose + NAD+ + H2O = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Ammonia + NADH + H+
[Fig] 1.4.1.- : dTDP-3-amino-2,3,6-trideoxy-D-threo-hexopyranos-4-ulose + NADP+ + H2O = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Ammonia + NADPH
[Fig] 1.4.1.- : dTDP-3-amino-2,3,6-trideoxy-D-threo-hexopyranos-4-ulose + NADP+ + H2O = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Ammonia + NADPH + H+
[Fig] 1.4.3.- : dTDP-3-amino-2,3,6-trideoxy-D-threo-hexopyranos-4-ulose + H2O + O2 = dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + Ammonia + H2O2
[Fig] 2.6.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + L-Glutamate = dTDP-3-amino-2,3,6-trideoxy-D-threo-hexopyranos-4-ulose + 2-Ketoglutaric acid
[Fig] 4.2.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O = dTDP-4-dehydro-6-deoxy-alpha-D-glucose
[Fig] 4.2.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O = dTDP-4-dehydro-6-deoxy-D-galactose
[Fig] 4.2.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O = 4,6-Dideoxy-4-oxo-dTDP-D-glucose
[Fig] 4.2.1.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran + H2O = dTDP-4-oxo-6-deoxy-D-allose
[Fig] 5.-.-.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran = dTDP 1-ester with (6S)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran
[Fig] 5.3.2.- : dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran = dTDP-3,4-dioxo-2,6-dideoxy-D-glucose

Reported reactions

No reported reactions found.

GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.