GREP C07478

Selected compound(s)

C07478 2-Hydroxy-5-methyl-cis,cis-muconate

Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions | Reported reactions]

Suggested reactions

[Fig] 1.2.1.- : (2E,4Z)-2-Hydroxy-5-methyl-6-oxohexa-2,4-dienoate + H2O + NAD+ = 2-Hydroxy-5-methyl-cis,cis-muconate + NADH + H+
[Fig] 1.2.1.- : (2E,4Z)-2-Hydroxy-5-methyl-6-oxohexa-2,4-dienoate + H2O + NADP+ = 2-Hydroxy-5-methyl-cis,cis-muconate + NADPH + H+
[Fig] 1.2.3.- : (2E,4Z)-2-Hydroxy-5-methyl-6-oxohexa-2,4-dienoate + H2O + O2 = 2-Hydroxy-5-methyl-cis,cis-muconate + H2O2
[Fig] 2.1.1.- : 2-Hydroxymuconate + S-Adenosyl-L-methionine = 2-Hydroxy-5-methyl-cis,cis-muconate + S-Adenosyl-L-homocysteine
[Fig] 2.1.1.- : 2-Hydroxymuconate + S-Adenosyl-L-methionine = 2-Hydroxy-5-methyl-cis,cis-muconate + S-Adenosyl-L-homocysteine + H+
[Fig] 3.3.2.- : 2-Hydroxy-5-methyl-cis,cis-muconate + H2O = 2-Hydroxymuconate + Methanol

Reported reactions

[Fig] EC 1.2.1.32 : (2E,4Z)-2-Hydroxy-5-methyl-6-oxohexa-2,4-dienoate + NAD+ + H2O = 2-Hydroxy-5-methyl-cis,cis-muconate + NADH + H+
[Fig] EC 5.3.2.- : 2-Hydroxy-5-methyl-cis,cis-muconate = 2-Oxo-5-methyl-cis-muconate

GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.