Selected compound(s)
- C04718 1,6,6-Trimethyl-2,7-dioxabicyclo[3.2.2]nonan-3-one
Each orphan metabolite is emphasized in bold.
Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions |
Reported reactions]
Suggested reactions
- [Fig] 1.14.11.- : (1R,4S)-1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octan-6-one + O2 + 2-Ketoglutaric acid = 1,6,6-Trimethyl-2,7-dioxabicyclo[3.2.2]nonan-3-one + CO2 + Butanedionic acid
- [Fig] 1.14.13.- : 1,6,6-Trimethyl-2,7-dioxabicyclo[3.2.2]nonan-3-one + H2O + NAD+ = (1R,4S)-1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octan-6-one + NADH + O2 + H+
- [Fig] 1.14.16.- : 1,6,6-Trimethyl-2,7-dioxabicyclo[3.2.2]nonan-3-one + 6,7-Dihydrobiopterin + H2O = (1R,4S)-1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octan-6-one + 2-Amino-6-(1,2-dihydroxypropyl)-5,6,7,8-tetrahydoro-4(1H)- pteridinone + O2
- [Fig] 1.14.17.- : (1R,4S)-1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octan-6-one + Vitamin C + O2 = 1,6,6-Trimethyl-2,7-dioxabicyclo[3.2.2]nonan-3-one + Dehydroascorbate + H2O
Reported reactions
- [Fig] EC 1.14.13.51 : (1R,4S)-1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octan-6-one + O2 + NADPH + H+ = 1,6,6-Trimethyl-2,7-dioxabicyclo[3.2.2]nonan-3-one + NADP+ + H2O
GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.