GREP C03590

Selected compound(s)

C03590 4-Hydroxybenzoylformate

Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions | Reported reactions]

Suggested reactions

[Fig] 1.1.1.- : (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + NAD+ = 4-Hydroxybenzoylformate + NADH + H+
[Fig] 1.1.1.- : 4-Hydroxybenzoylformate + NADPH + H+ = (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + NADP+
[Fig] 1.1.3.- : (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + O2 = 4-Hydroxybenzoylformate + H2O2
[Fig] 1.1.4.- : 4-Hydroxybenzoylformate + 1,4-Dithiothreitol = (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + Oxidized dithiothreitol
[Fig] 1.1.5.- : (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + Coenzyme F420 = 4-Hydroxybenzoylformate + Reduced coenzyme F420
[Fig] 1.1.5.- : 4-Hydroxybenzoylformate + Reduced thioredoxin = (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + Oxidized thioredoxin
[Fig] 1.1.5.- : 4-Hydroxybenzoylformate + CoQH2 = (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + CoQ
[Fig] 1.1.99.- : (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + FAD = 4-Hydroxybenzoylformate + FADH2
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + H2O + NAD+ = 4-Hydroxybenzoylformate + NADH + Ammonia
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + H2O + NAD+ = 4-Hydroxybenzoylformate + NADH + Ammonia + H+
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + H2O + NAD+ = 4-Hydroxybenzoylformate + NADH + H+ + Ammonia
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + H2O + NADP+ = 4-Hydroxybenzoylformate + NADPH + Ammonia
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + H2O + NADP+ = 4-Hydroxybenzoylformate + NADPH + Ammonia + H+
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + H2O + NADP+ = 4-Hydroxybenzoylformate + NADPH + H+ + Ammonia
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + NAD+ + H2O = 4-Hydroxybenzoylformate + Ammonia + NADH
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + NAD+ + H2O = 4-Hydroxybenzoylformate + Ammonia + NADH + H+
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + NADP+ + H2O = 4-Hydroxybenzoylformate + Ammonia + NADPH
[Fig] 1.4.1.- : D-4-Hydroxyphenylglycine + NADP+ + H2O = 4-Hydroxybenzoylformate + Ammonia + NADPH + H+
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + H2O + NAD+ = 4-Hydroxybenzoylformate + NADH + Ammonia
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + H2O + NAD+ = 4-Hydroxybenzoylformate + NADH + Ammonia + H+
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + H2O + NAD+ = 4-Hydroxybenzoylformate + NADH + H+ + Ammonia
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + H2O + NADP+ = 4-Hydroxybenzoylformate + NADPH + Ammonia
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + H2O + NADP+ = 4-Hydroxybenzoylformate + NADPH + Ammonia + H+
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + H2O + NADP+ = 4-Hydroxybenzoylformate + NADPH + H+ + Ammonia
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + NAD+ + H2O = 4-Hydroxybenzoylformate + Ammonia + NADH
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + NAD+ + H2O = 4-Hydroxybenzoylformate + Ammonia + NADH + H+
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + NADP+ + H2O = 4-Hydroxybenzoylformate + Ammonia + NADPH
[Fig] 1.4.1.- : L-4-Hydroxyphenylglycine + NADP+ + H2O = 4-Hydroxybenzoylformate + Ammonia + NADPH + H+
[Fig] 1.4.3.- : D-4-Hydroxyphenylglycine + H2O + O2 = 4-Hydroxybenzoylformate + Ammonia + H2O2
[Fig] 1.4.3.- : L-4-Hydroxyphenylglycine + H2O + O2 = 4-Hydroxybenzoylformate + Ammonia + H2O2
[Fig] 2.1.2.- : 4-Hydroxybenzoylformate + THF = 4-Hydroxybenzaldehyde + 10-Formyl-THF
[Fig] 2.6.1.- : D-4-Hydroxyphenylglycine + Pyridoxal 5'-phosphate = 4-Hydroxybenzoylformate + Pyridoxamine 5'-phosphate
[Fig] 2.6.1.- : 4-Hydroxybenzoylformate + L-Glutamate = D-4-Hydroxyphenylglycine + 2-Ketoglutaric acid
[Fig] 2.6.1.- : 4-Hydroxybenzoylformate + L-Glutamate = L-4-Hydroxyphenylglycine + 2-Ketoglutaric acid
[Fig] 2.6.1.- : L-4-Hydroxyphenylglycine + Pyridoxal 5'-phosphate = 4-Hydroxybenzoylformate + Pyridoxamine 5'-phosphate
[Fig] 3.7.1.- : 4-Hydroxybenzoylformate + H2O = 4-Hydroxybenzaldehyde + Formate
[Fig] 4.1.1.- : 4-Hydroxybenzaldehyde + CO2 = 4-Hydroxybenzoylformate
[Fig] 6.4.1.- : 4-Hydroxybenzaldehyde + ATP + Acid carbonate = 4-Hydroxybenzoylformate + ADP + Orthophosphate
[Fig] 6.4.1.- : 4-Hydroxybenzoylformate + ADP + Orthophosphate = 4-Hydroxybenzaldehyde + Formate + ATP

Reported reactions

[Fig] EC 2.6.1.72 : D-4-Hydroxyphenylglycine + 2-Ketoglutaric acid = 4-Hydroxybenzoylformate + L-Glutamate
[Fig] EC 4.1.1.7 : 4-Hydroxybenzoylformate = 4-Hydroxybenzaldehyde + CO2
[Fig] EC 1.1.99.- : (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + Acceptor = 4-Hydroxybenzoylformate + Reduced acceptor

GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.