GREP C02673

Selected compound(s)

C02673 16-Methoxy-2,3-dihydro-3-hydroxy-N-methyltabersonine

Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions | Reported reactions]

Suggested reactions

[Fig] 1.14.11.- : 16-Methoxy-2,3-dihydro-3-hydroxy-N-methyltabersonine + O2 + 2-Ketoglutaric acid = 17-O-Deacetylvindoline + CO2 + Butanedionic acid
[Fig] 2.1.1.- : 16-Methoxy-2,3-dihydro-3-hydroxytabersonine + S-Adenosyl-L-methionine = 16-Methoxy-2,3-dihydro-3-hydroxy-N-methyltabersonine + S-Adenosyl-L-homocysteine + H+
[Fig] 2.1.1.156 2.1.1.157 2.1.1.- : 16-Methoxy-2,3-dihydro-3-hydroxytabersonine + S-Adenosyl-L-methionine = 16-Methoxy-2,3-dihydro-3-hydroxy-N-methyltabersonine + S-Adenosyl-L-homocysteine
[Fig] 3.1.1.- : 16-Methoxy-2,3-dihydro-3-hydroxy-N-methyltabersonine + H2O = 16-Methoxy-2,3-dihydro-3-hydroxytabersonine + Methanol

Reported reactions

[Fig] EC 2.1.1.99 : S-Adenosyl-L-methionine + 16-Methoxy-2,3-dihydro-3-hydroxytabersonine = S-Adenosyl-L-homocysteine + 16-Methoxy-2,3-dihydro-3-hydroxy-N-methyltabersonine
[Fig] EC 1.14.11.20 : 16-Methoxy-2,3-dihydro-3-hydroxy-N-methyltabersonine + 2-Ketoglutaric acid + O2 = 17-O-Deacetylvindoline + Butanedionic acid + CO2

GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.