GREP C02137

Selected compound(s)

C02137 Benzoylformate

Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions | Reported reactions]

Suggested reactions

[Fig] 1.1.1.- : (R)-2-Hydroxy-2-phenylacetate + NAD+ = Benzoylformate + NADH + H+
[Fig] 1.1.1.- : (S)-2-Hydroxy-2-phenylacetate + NAD+ = Benzoylformate + NADH + H+
[Fig] 1.1.1.- : Benzoylformate + NADPH + H+ = (R)-2-Hydroxy-2-phenylacetate + NADP+
[Fig] 1.1.1.- : Benzoylformate + NADPH + H+ = (S)-2-Hydroxy-2-phenylacetate + NADP+
[Fig] 1.1.3.- : (R)-2-Hydroxy-2-phenylacetate + O2 = Benzoylformate + H2O2
[Fig] 1.1.3.- : (S)-2-Hydroxy-2-phenylacetate + O2 = Benzoylformate + H2O2
[Fig] 1.1.4.- : Benzoylformate + 1,4-Dithiothreitol = (R)-2-Hydroxy-2-phenylacetate + Oxidized dithiothreitol
[Fig] 1.1.4.- : Benzoylformate + 1,4-Dithiothreitol = (S)-2-Hydroxy-2-phenylacetate + Oxidized dithiothreitol
[Fig] 1.1.5.- : (R)-2-Hydroxy-2-phenylacetate + Coenzyme F420 = Benzoylformate + Reduced coenzyme F420
[Fig] 1.1.5.- : (S)-2-Hydroxy-2-phenylacetate + Coenzyme F420 = Benzoylformate + Reduced coenzyme F420
[Fig] 1.1.5.- : Benzoylformate + Reduced thioredoxin = (R)-2-Hydroxy-2-phenylacetate + Oxidized thioredoxin
[Fig] 1.1.5.- : Benzoylformate + Reduced thioredoxin = (S)-2-Hydroxy-2-phenylacetate + Oxidized thioredoxin
[Fig] 1.1.5.- : Benzoylformate + CoQH2 = (R)-2-Hydroxy-2-phenylacetate + CoQ
[Fig] 1.1.5.- : Benzoylformate + CoQH2 = (S)-2-Hydroxy-2-phenylacetate + CoQ
[Fig] 1.1.99.- : (R)-2-Hydroxy-2-phenylacetate + FAD = Benzoylformate + FADH2
[Fig] 1.1.99.- : (S)-2-Hydroxy-2-phenylacetate + FAD = Benzoylformate + FADH2
[Fig] 1.2.1.- : Benzoylformate + NADPH = Aromatic primary alcohol + NADP+ + CO2
[Fig] 1.2.1.- : Benzoylformate + NADPH = Aromatic primary alcohol + NADP+ + CO2 + H+
[Fig] 1.2.1.- : Aromatic primary alcohol + NAD+ + CO2 + H+ = Benzoylformate + NADH
[Fig] 1.2.1.- : Aromatic primary alcohol + NAD+ + CO2 = Benzoylformate + NADH
[Fig] 2.1.2.- : Benzoylformate + THF = Benzaldehyde + 10-Formyl-THF
[Fig] 3.7.1.- : Benzoylformate + H2O = Benzaldehyde + Formate
[Fig] 4.1.1.- : Benzaldehyde + CO2 = Benzoylformate
[Fig] 6.4.1.- : Benzaldehyde + ATP + Acid carbonate = Benzoylformate + ADP + Orthophosphate
[Fig] 6.4.1.- : Benzoylformate + ADP + Orthophosphate = Benzaldehyde + Formate + ATP

Reported reactions

[Fig] EC 1.2.1.58 : Benzoylformate + CoA + NAD+ = Benzoyl-CoA + CO2 + NADH
[Fig] EC 1.2.1.- : (R)-2-Hydroxy-2-phenylacetate + NAD+ = Benzoylformate + NADH + H+
[Fig] EC 1.1.1.- : (S)-2-Hydroxy-2-phenylacetate + NAD+ = Benzoylformate + NADH
[Fig] EC 1.1.99.- : (S)-2-Hydroxy-2-phenylacetate + Acceptor = Benzoylformate + Reduced acceptor
[Fig] EC 4.1.1.7 : Benzoylformate = Benzaldehyde + CO2

GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.