GREP C00650

Selected compound(s)

C00650 4-Hydroxymandelonitrile

Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions | Reported reactions]

Suggested reactions

[Fig] 1.7.1.- : 4-Hydroxymandelonitrile + NADPH + H+ = (Z)-4-Hydroxyphenylacetaldehyde-oxime + NADP+
[Fig] 1.7.1.- : (Z)-4-Hydroxyphenylacetaldehyde-oxime + NAD+ = 4-Hydroxymandelonitrile + NADH + H+
[Fig] 1.7.3.- : (Z)-4-Hydroxyphenylacetaldehyde-oxime + O2 = 4-Hydroxymandelonitrile + H2O2
[Fig] 1.7.4.- : 4-Hydroxymandelonitrile + 1,4-Dithiothreitol = (Z)-4-Hydroxyphenylacetaldehyde-oxime + Oxidized dithiothreitol
[Fig] 1.7.5.- : 4-Hydroxymandelonitrile + CoQH2 = (Z)-4-Hydroxyphenylacetaldehyde-oxime + CoQ
[Fig] 1.7.99.- : (Z)-4-Hydroxyphenylacetaldehyde-oxime + FAD = 4-Hydroxymandelonitrile + FADH2
[Fig] 1.7.99.- : (Z)-4-Hydroxyphenylacetaldehyde-oxime + Coenzyme F420 = 4-Hydroxymandelonitrile + Reduced coenzyme F420
[Fig] 1.14.11.- : 4-Hydroxybenzyl cyanide + O2 + 2-Ketoglutaric acid = 4-Hydroxymandelonitrile + CO2 + Butanedionic acid
[Fig] 2.1.2.- : 4-Hydroxymandelonitrile + THF = 4-Hydroxybenzaldehyde + 5-Formimidoyltetrahydrofolate
[Fig] 3.2.1.- : Taxiphyllin + H2O = D-Glucose + 4-Hydroxymandelonitrile
[Fig] 3.2.1.- : Taxiphyllin + H2O = D-Hexose + 4-Hydroxymandelonitrile

Reported reactions

[Fig] EC 1.14.13.- : (Z)-4-Hydroxyphenylacetaldehyde-oxime + NADPH + H+ + O2 = 4-Hydroxymandelonitrile + NADP+ + 2 H2O
[Fig] EC 4.1.2.11 : 4-Hydroxymandelonitrile = HCN + 4-Hydroxybenzaldehyde
[Fig] EC 1.14.13.42 : 4-Hydroxybenzyl cyanide + O2 + NADPH = 4-Hydroxymandelonitrile + NADP+ + H2O
[Fig] EC 2.4.1.178 : UDP-glucose + 4-Hydroxymandelonitrile = UDP + Taxiphyllin

GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.