GREP 1.2.3.-

Selected EC sub-subclass(es)

1.2.3.-

The 4th digit is ignored (because this CGI only shows suggested reactions, not reported reactions).Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.
[Suggested reactions | Reported reactions]

Suggested reactions

Each orphan metabolite is emphasized in bold. Click [Fig] on the left hand, and the image of the reaction is shown.

[Fig] 1.2.3.- : Glyoxalate + H2O + O2 = Ethanedioic acid + H2O2
[Fig] 1.2.3.- : D-Glyceraldehyde 3-phosphate + H2O + O2 = 3-Phospho-D-glycerate + H2O2
[Fig] 1.2.3.- : 3-Oxopropanoate + H2O + O2 = Malonate + H2O2
[Fig] 1.2.3.- : Succinate semialdehyde + H2O + O2 = Butanedionic acid + H2O2
[Fig] 1.2.3.- : Pyridoxal + H2O + O2 = 4-Pyridoxate + H2O2
[Fig] 1.2.3.- : Pyridoxal + O2 = 4-Pyridoxolactone + H2O2
[Fig] 1.2.3.- : Benzaldehyde + H2O + O2 = Benzoate + H2O2
[Fig] 1.2.3.- : Benzaldehyde + H2O + O2 = Benzoate + H2O2
[Fig] 1.2.3.- : D-Erythrose 4-phosphate + H2O + O2 = 4-Phospho-D-erythronate + H2O2
[Fig] 1.2.3.- : Retinal + H2O + O2 = (all-E)-3,7-Dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4,6,8- nonatetraenoic acid + H2O2
[Fig] 1.2.3.- : (S)-Lactaldehyde + H2O + O2 = L-Lactate + H2O2
[Fig] 1.2.3.- : 2,5-Dioxopentanoate + H2O + O2 = 2-Ketoglutaric acid + H2O2
[Fig] 1.2.3.- : Aspartate beta-semialdehyde + H2O + O2 = 2-Aminosuccinic acid + H2O2
[Fig] 1.2.3.- : 16-Hexadecanal + H2O + O2 = Cetylic acid + H2O2
[Fig] 1.2.3.- : 2-Oxoaldehyde + H2O + O2 = 2-Oxo acid + H2O2
[Fig] 1.2.3.- : 2-Ketopropionaldehyde + H2O + O2 = 2-Oxopropanoate + H2O2
[Fig] 1.2.3.- : 2-Ketopropionaldehyde + H2O + O2 = 2-Oxopropanoate + H2O2
[Fig] 1.2.3.- : 4-Aminobutanal + H2O + O2 = 4-Aminobutanoate + H2O2
[Fig] 1.2.3.- : 4-Aminobutanal + H2O + O2 = 4-Aminobutanoate + H2O2
[Fig] 1.2.3.- : Betaine aldehyde + H2O + O2 = Betaine + H2O2
[Fig] 1.2.3.- : Betaine aldehyde + H2O + CoQ = Betaine + CoQH2
[Fig] 1.2.3.- : D-Glyceraldehyde + H2O + O2 = (R)-Glycerate + H2O2
[Fig] 1.2.3.- : Phenylacetaldehyde + H2O + O2 = Benzeneacetiic acid + H2O2
[Fig] 1.2.3.- : 3-Dehydro-L-gulonate + H2O + O2 = Galactarate + H2O2
[Fig] 1.2.3.- : 4-Hydroxybenzaldehyde + H2O + O2 = 4-Hydroxybenzoate + H2O2
[Fig] 1.2.3.- : 4-Hydroxybenzaldehyde + H2O + O2 = 4-Hydroxybenzoate + H2O2
[Fig] 1.2.3.- : 2-(Indol-3-yl)acetaldehyde + H2O + O2 = Indole-3-acetate + H2O2
[Fig] 1.2.3.- : 2-Hydroxymuconate semialdehyde + H2O + O2 = 2-Hydroxymuconate + H2O2
[Fig] 1.2.3.- : 4-Hydroxy-3-methoxy-benzaldehyde + H2O + O2 = 4-Hydroxy-3-methoxybenzoate + H2O2
[Fig] 1.2.3.- : 4-Hydroxy-3-methoxy-benzaldehyde + H2O + O2 = 4-Hydroxy-3-methoxybenzoate + H2O2
[Fig] 1.2.3.- : 4-Coumarate + O2 = 7-Hydroxycoumarin + H2O2
[Fig] 1.2.3.- : Cinnamaldehyde + H2O + O2 = trans-Cinnamate + H2O2
[Fig] 1.2.3.- : Cinnamaldehyde + H2O + O2 = Cinnamic acid + H2O2
[Fig] 1.2.3.- : (R)-Lactaldehyde + H2O + O2 = (R)-Lactate + H2O2
[Fig] 1.2.3.- : (R)-Lactaldehyde + H2O + O2 = (R)-Lactate + H2O2
[Fig] 1.2.3.- : (R)-4-Dehydropantoate + H2O + O2 = (R)-3,3-Dimethylmalate + H2O2
[Fig] 1.2.3.- : 4-Trimethylammoniobutanal + H2O + O2 = 4-Trimethylammoniobutanoate + H2O2
[Fig] 1.2.3.- : L-Glutamate 5-semialdehyde + H2O + O2 = L-Glutamate + H2O2
[Fig] 1.2.3.- : 3,4-Dihydroxy-trans-cinnamate + O2 = 7,8-Dihydroxycoumarin + H2O2
[Fig] 1.2.3.- : 3,4-Dihydroxy-trans-cinnamate + O2 = Esculetin + H2O2
[Fig] 1.2.3.- : 3alpha,7alpha,12alpha-Trihydroxy-5beta-cholestan-26-al + H2O + O2 = 3alpha,7alpha,12alpha-Trihydroxy-5beta-cholestan-26-oate + H2O2
[Fig] 1.2.3.- : 3-Methoxy-4-hydroxy-trans-cinnamate + O2 = Scopoletin + H2O2
[Fig] 1.2.3.- : Aldohexose + H2O + O2 = D-Gluco-hexonic acid + H2O2
[Fig] 1.2.3.- : L-Histidinal + H2O + O2 = L-Histidine + H2O2
[Fig] 1.2.3.- : 4-Oxobutanoate + H2O + O2 = Butanedionic acid + H2O2
[Fig] 1.2.3.- : Formylpyruvate + H2O + O2 = keto-Oxaloacetate + H2O2
[Fig] 1.2.3.- : Perillaldehyde + H2O + O2 = Perillic acid + H2O2
[Fig] 1.2.3.- : 4-Guanidinobutanal + H2O + O2 = 4-Guanidinobutanoate + H2O2
[Fig] 1.2.3.- : 4-Hydroxy-3-methoxycinnamaldehyde + H2O + O2 = 3-Methoxy-4-hydroxy-trans-cinnamate + H2O2
[Fig] 1.2.3.- : 4-Hydroxy-3-methoxycinnamaldehyde + H2O + O2 = 3-Methoxy-4-hydroxy-trans-cinnamate + H2O2
[Fig] 1.2.3.- : 4,5-Dioxopentanoate + H2O + O2 = 2-Ketoglutaric acid + H2O2
[Fig] 1.2.3.- : 2-Carboxybenzaldehyde + H2O + O2 = 1,2-Benzenedicarboxylic acid + H2O2
[Fig] 1.2.3.- : 3-Hydroxybenzaldehyde + H2O + O2 = 3-Hydroxybenzoate + H2O2
[Fig] 1.2.3.- : 2-Phosphonoacetaldehyde + H2O + O2 = Phosphonoacetate + H2O2
[Fig] 1.2.3.- : 5-Oxopentanoate + H2O + O2 = 1,3-Propanedicarboxylic acid + H2O2
[Fig] 1.2.3.- : (S)-4-Amino-5-oxopentanoate + H2O + O2 = L-Glutamate + H2O2
[Fig] 1.2.3.- : 2-(4-Hydroxyphenyl)acetaldehyde + H2O + O2 = 4-Hydroxyphenylacetate + H2O2
[Fig] 1.2.3.- : 2-Aminomuconate 6-semialdehyde + H2O + O2 = 2-Aminomuconate + H2O2
[Fig] 1.2.3.- : 3,4-Dihydroxyphenylacetaldehyde + H2O + O2 = 3,4-Dihydroxyphenyl acetate + H2O2
[Fig] 1.2.3.- : 2-Aminoadipate 6-semialdehyde + H2O + O2 = L-2-Aminoadipate + H2O2
[Fig] 1.2.3.- : (Z)-2-Methyl-5-isopropylhexa-2,5-dienal + H2O + O2 = cis-2-Methyl-5-isopropylhexa-2,5-dienoic acid + H2O2
[Fig] 1.2.3.- : 4-Carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + H2O + O2 = 4-Carboxy-2-hydroxy-cis,cis-muconate + H2O2
[Fig] 1.2.3.- : 2-Hydroxy-5-carboxymethylmuconate semialdehyde + H2O + O2 = 5-Carboxymethyl-2-hydroxymuconate + H2O2
[Fig] 1.2.3.- : 2-Hydroxy-5-carboxymethylmuconate semialdehyde + H2O + O2 = 5-Carboxymethyl-2-hydroxymuconate + H2O2
[Fig] 1.2.3.- : Imidazole acetaldehyde + H2O + O2 = 4-Imidazoleacetate + H2O2
[Fig] 1.2.3.- : 3alpha,7alpha-Dihydroxy-5beta-cholestan-26-al + H2O + O2 = 3alpha,7alpha-Dihydroxy-5beta-cholestanate + H2O2
[Fig] 1.2.3.- : 3,4-Dihydroxymandelaldehyde + H2O + O2 = 3,4-Dihydroxymandelate + H2O2
[Fig] 1.2.3.- : 3-Methoxy-4-hydroxyphenylacetaldehyde + H2O + O2 = Homovanillate + H2O2
[Fig] 1.2.3.- : 3-Methoxy-4-hydroxyphenylglycolaldehyde + H2O + O2 = 3-Methoxy-4-hydroxymandelate + H2O2
[Fig] 1.2.3.- : Gentisate aldehyde + H2O + O2 = 2,5-Dihydroxybenzoate + H2O2
[Fig] 1.2.3.- : Gentisate aldehyde + H2O + O2 = 2,5-Dihydroxybenzoate + H2O2
[Fig] 1.2.3.- : Sinapaldehyde + H2O + O2 = 3,5-Dimethoxy-4-hydroxycinnamic acid + H2O2
[Fig] 1.2.3.- : 5-Hydroxyindoleacetaldehyde + H2O + O2 = 5-Hydroxyindoleacetate + H2O2
[Fig] 1.2.3.- : 5-(2'-Formylethyl)-4,6-dihydroxypicolinate + H2O + O2 = 5-(2'-Carboxyethyl)-4,6-dihydroxypicolinate + H2O2
[Fig] 1.2.3.- : beta-Aminopropion aldehyde + H2O + O2 = beta-Alanine + H2O2
[Fig] 1.2.3.- : beta-Aminopropion aldehyde + H2O + O2 = beta-Alanine + H2O2
[Fig] 1.2.3.- : 1-Methylimidazole-4-acetaldehyde + H2O + O2 = 1-Methyl-4-imidazoleacetic acid + H2O2
[Fig] 1.2.3.- : Thiamine aldehyde + H2O + O2 = Thiamin acetic acid + H2O2
[Fig] 1.2.3.- : N2-Succinyl-L-glutamate 5-semialdehyde + H2O + O2 = N2-Succinyl-L-glutamate + H2O2
[Fig] 1.2.3.- : N4-Acetylaminobutanal + H2O + O2 = 4-Acetamidobutanoate + H2O2
[Fig] 1.2.3.- : L-4-Hydroxyglutamate semialdehyde + H2O + O2 = L-erythro-4-Hydroxyglutamate + H2O2
[Fig] 1.2.3.- : 3-Oxopropionyl-CoA + H2O + O2 = Malonyl-CoA + H2O2
[Fig] 1.2.3.- : 3-Oxopropionyl-CoA + H2O + O2 = omega-Carboxyacyl-CoA + H2O2
[Fig] 1.2.3.- : 2-Hydroxypropanal + H2O + O2 = 2-Hydroxypropanoic acid + H2O2
[Fig] 1.2.3.- : (S)-Methylmalonate semialdehyde + H2O + O2 = Methylmalonate + H2O2
[Fig] 1.2.3.- : (S)-Methylmalonate semialdehyde + H2O + O2 = Methylmalonate + H2O2
[Fig] 1.2.3.- : 2-Methyl-3-hydroxy-5-formylpyridine-4-carboxylate + H2O + O2 = 3-Hydroxy-2-methylpyridine-4,5-dicarboxylate + H2O2
[Fig] 1.2.3.- : Isopyridoxal + H2O + O2 = 3-Hydroxy-4-hydroxymethyl-2-methylpyridine-5-carboxylate + H2O2
[Fig] 1.2.3.- : Gibberellin A12 aldehyde + H2O + O2 = Gibberellin A12 + H2O2
[Fig] 1.2.3.- : 6-Oxohexanoate + H2O + O2 = Adipate + H2O2
[Fig] 1.2.3.- : Salicylaldehyde + H2O + O2 = Salicylate + H2O2
[Fig] 1.2.3.- : Cuminaldehyde + H2O + O2 = p-Cumate + H2O2
[Fig] 1.2.3.- : 4-Hydroxymuconic semialdehyde + H2O + O2 = 2-Maleylacetate + H2O2
[Fig] 1.2.3.- : 3-Chloroallyl aldehyde + H2O + O2 = trans-3-Chloroacrylic acid + H2O2
[Fig] 1.2.3.- : 3-Chloroallyl aldehyde + H2O + O2 = cis-3-Chloroacrylic acid + H2O2
[Fig] 1.2.3.- : 4-Chlorobenzaldehyde + H2O + O2 = 4-Chlorobenzoate + H2O2
[Fig] 1.2.3.- : 4-Formylbenzenesulfonate + H2O + O2 = 4-Sulfobenzoate + H2O2
[Fig] 1.2.3.- : 4-Toluylaldehyde + H2O + O2 = 4-Methylbenzoic acid + H2O2
[Fig] 1.2.3.- : (2E,4Z)-2-Hydroxy-5-methyl-6-oxohexa-2,4-dienoate + H2O + O2 = 2-Hydroxy-5-methyl-cis,cis-muconate + H2O2
[Fig] 1.2.3.- : 3-Methylbenzaldehyde + H2O + O2 = beta-Bethylbenzoic acid + H2O2
[Fig] 1.2.3.- : 2-Methylbenzaldehyde + H2O + O2 = 2-methylbenzoic acid + H2O2
[Fig] 1.2.3.- : Caffeic acid 3-glucoside + O2 = Esculin + H2O2
[Fig] 1.2.3.- : Cinnamic acid + O2 = 1,2-Benzopyrone + H2O2
[Fig] 1.2.3.- : 1-Hydroxy-2-naphthaldehyde + H2O + O2 = 1-Hydroxy-2-naphthoate + H2O2
[Fig] 1.2.3.- : 3beta-Hydroxy-4beta-methyl-5alpha-cholest-7-ene-4alpha-carbaldehyde + H2O + O2 = 3beta-Hydroxy-4beta-methyl-5alpha-cholest-7-ene-4alpha-carboxylate + H2O2
[Fig] 1.2.3.- : 8-Epiiridotrial glucoside + H2O + O2 = 8-Epideoxyloganic acid + H2O2
[Fig] 1.2.3.- : Iridotrial glucoside + H2O + O2 = 7-Deoxyloganate + H2O2
[Fig] 1.2.3.- : Tarennoside + H2O + O2 = Geniposidic acid + H2O2
[Fig] 1.2.3.- : Gibberellin A14 aldehyde + H2O + O2 = Gibberellin A14 + H2O2
[Fig] 1.2.3.- : Neoabietal + H2O + O2 = Neoabietic acid + H2O2
[Fig] 1.2.3.- : Levopimarinal + H2O + O2 = L-Pimaric acid + H2O2
[Fig] 1.2.3.- : Abietal + H2O + O2 = Abietate + H2O2
[Fig] 1.2.3.- : Gibberellin A53 aldehyde + H2O + O2 = Gibberellin A53 + H2O2
[Fig] 1.2.3.- : Myrtenal + H2O + O2 = Myrtenic acid + H2O2
[Fig] 1.2.3.- : trans-2-Methyl-5-isopropylhexa-2,5-dienal + H2O + O2 = trans-2-Methyl-5-isopropylhexa-2,5-dienoic acid + H2O2
[Fig] 1.2.3.- : Apiforol + O2 = Licodione + H2O2
[Fig] 1.2.3.- : UDP-3-keto-D-glucose + H2O + O2 = UDP-D-glucuronate + H2O2
[Fig] 1.2.3.- : 3-Dimethylallyl-4-hydroxybenzaldehyde + H2O + O2 = 3-Dimethylallyl-4-hydroxybenzoate + H2O2
[Fig] 1.2.3.- : 2-Hydroxy-3-methylbenzaldehyde + H2O + O2 = 3-Methylsalicylate + H2O2
[Fig] 1.2.3.- : 2-Hydroxyisophthalaldehydic acid + H2O + O2 = 2-Hydroxy-1,3-benzenedicarboxylic acid + H2O2
[Fig] 1.2.3.- : 2-Naphthaldehyde + H2O + O2 = 2-Naphthalenecarboxylic acid + H2O2
[Fig] 1.2.3.- : 2-Hydroxy-4-hydroxymethyl-benzaldehyde + H2O + O2 = 2-Hydroxy-4-hydroxymethylbenzoic acid + H2O2

Reported reactions

[Fig] EC 1.2.3.- : 2 3-(4-Hydroxyphenyl)pyruvate + O2 = 2 4-Hydroxyphenylacetate + 2 CO2
[Fig] EC 1.2.3.7 : O2 + 2 2-(Indol-3-yl)acetaldehyde = 2 Indole-3-acetate + 2 H2O
[Fig] EC 1.2.3.3 : 2-Oxopropanoate + Orthophosphate + O2 = Acetyl phosphate + H2O2 + CO2
[Fig] EC 1.2.3.6 : 2-Oxopropanoate + CoA + O2 = H2O2 + Acetyl-CoA + CO2
[Fig] EC 1.2.3.4 : Ethanedioic acid + O2 = H2O2 + 2 CO2
[Fig] EC 1.2.3.5 : Glyoxalate + O2 + H2O = Ethanedioic acid + H2O2
[Fig] EC 1.2.3.1 : Aldehyde + O2 + H2O = Carboxylate + H2O2
[Fig] EC 1.2.3.9 : Aromatic aldehyde + O2 = Aromatic acid + H2O2
[Fig] EC 1.2.3.8 : Pyridoxal + O2 + H2O = 4-Pyridoxate + O2-
[Fig] EC 1.2.3.11 : Retinal + O2 + H2O = (all-E)-3,7-Dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4,6,8- nonatetraenoic acid + H2O2
[Fig] EC 1.2.3.1 : Gentisate aldehyde + NAD+ + H2O = 2,5-Dihydroxybenzoate + NADH
[Fig] EC 1.2.3.1 : 2,5-Dihydroxybenzoate + H2O2 = Gentisate aldehyde + O2 + H2O
[Fig] EC 1.2.3.7 : 2-(Indol-3-yl)acetaldehyde + O2 + H2O = Indole-3-acetate + H2O2
[Fig] EC 1.2.3.1 : Methylmalonate + O2- = (S)-Methylmalonate semialdehyde + O2 + H2O
[Fig] EC 1.2.3.1 : 1-Methylnicotinamide + 2 O2 + 2 H2O = N'-Methyl-4-pyridone-5-carboxamide + N'-Methyl-2-pyridone-5-carboxamide + 2 H2O2
[Fig] EC 1.2.3.1 : 5-Hydroxyindoleacetaldehyde + O2 + H2O = 5-Hydroxyindoleacetate + O2
[Fig] EC 1.2.-.- : 4-Chlorobenzoate = 4-Chlorobenzaldehyde + H2O
[Fig] EC 1.-.-.- : 6-Deoxyerythronolide B + O2 = Erythronolide B
[Fig] EC 1.2.3.9 : 4-Hydroxy-3-methoxybenzoate + NAD+ + H2O = 4-Hydroxy-3-methoxy-benzaldehyde + O2 + NADH
[Fig] EC 1.2.-.- : Myrtenal + H2O + Acceptor = Myrtenic acid + Reduced acceptor
[Fig] EC 1.2.3.- : 2-Hydroxyisophthalaldehydic acid + O2 + H2O = 2-Hydroxy-1,3-benzenedicarboxylic acid + H2O2

GREP v1.0.2 http://bisscat.org/GREP/
Developed by Masaaki Kotera (2008), Department of Biochemistry, Trinity College Dublin.
Science Foundation of Ireland is gratefully acknowledged.